Study of Adsorption of Lead Metal (Pb) Using Chemically Acti-vated (Nypa Fruticans) Powder Biosorbent
Abstract
Heavy metal contamination in the environment is now quite concerning, and it is hazardous if it enters the body. Continuous human interaction with heavy metal lead (Pb) will result in various health problems. Nipa palm is a palm (Palma) thrives in mangrove forest habitats or along the seashore, with a cellulose content of 35.1%, 26.4% hemicellulose, and 17.8% lignin. This research aims to see if palm fronds (Nypa fruticans) can be used as a biosorbent to remove the heavy metal Pb in artificial solutions. The analysis was carried out in phases, beginning with the creation of biosorbents from Nipah fronds by decreasing their size to powder and drying them in the sun, followed by analyzing the efficacy of the biosorbents and the number of functional groups using the FTIR instrument. The research was carried out by varying the particle size of the nipa palm frond adsorbent, namely 40, 60, and 80 mesh, as well as contact times of 30, 60, 90, and 100 minutes, to determine the level of adsorption absorption and the adsorption mechanism using the Langmuir and Freundlich isotherm equation approach. The Pb solution used had a concentration of 20 ppm. The results showed that the maximum metal absorption level was 99.29% at a particle size of 80 mesh with a contact time of 100 minutes. The absorption mechanism is close to the Langmuir isotherm equation with R2 = 0.9998. It is suspected that the adsorption process occurs in one layer (monolayer) of the adsorbent.
Keywords
Full Text:
PDFReferences
arie febrianto Mulyadi, ika atsari Dewi, and P. Deoranto, “Pemanfaatan Kulit Buah Nipah Untuk Pembuatan Briket Bioarang,†J. Teknol. Pertan., vol. 14, no. april 2013, pp. 65–72, 2013.
P. Tamunaidu and S. Saka, “Chemical characterization of various parts of nipa palm (Nypa fruticans),†Ind. Crops Prod., vol. 34, no. 3, pp. 1423–1428, 2011, doi: 10.1016/j.indcrop.2011.04.020.
M. Muhammad, M. Meriatna, N. Afriani, and R. Mulyawan, “Oyster Shell Waste (Crassostrea Gigas) as A Cheap Adsorbent for Adsorption Of Methylene Blue Dyes: Equilibrium and Kinetics Studies,†Int. J. Eng. Sci. Inf. Technol., vol. 1, no. 4, pp. 95–102, 2021, doi: 10.52088/ijesty.v1i4.178.
A. Nugroho, N. L. Amanah, and R. G. Firdaus, “Adsorption study of mango peel activated carbon as iron removal for batik waste industry,†J. Rekayasa Proses, vol. 16, no. 1, p. 19, 2022, doi: 10.22146/jrekpros.69404.
R. Mangushev, Geotechnic, A. Osokin, Geotechnic, and Docent, “Construction of Deep Foundation Ditch under a Reconstructed Multi-storey Building on the Main Avenue of St.Petersburg,†2017, doi: 10.1016/j.proeng.2017.05.099.
R. Abu-El-Halawa and S. A. Zabin, “Removal efficiency of Pb, Cd, Cu and Zn from polluted water using dithiocarbamate ligands,†J. Taibah Univ. Sci., vol. 11, no. 1, pp. 57–65, 2017, doi: 10.1016/j.jtusci.2015.07.002.
B. Dwi Cahyono and D. Sulastri, “Development Of Electrical Installation Learning Me-dia With Delphi Language,†Int. J. Eng. Sci. Inf. Technol., vol. 1, no. 3, 2021, doi: 10.52088/ijesty.v1i3.81.
S. J. Safariyanti, W. Rahmalia, and A. Shofiyani, “Sintesis Dan Karakteristik Karbon Aktif Dari Tempurung Buah Nipah (Nypa fruticans) Menggunakan Aktivator Asam Klorida,†J. Kim. Khatulistiwa, vol. 7, no. 2, pp. 41–46, 2018.
S. Kumari and A. Harikrishnan, “Importance of Financial literacy For Sustainable Future Environment: A Research Among People In Rural Areas With Special Reference To Mandi District,Himachal Pradesh,†Int. J. Eng. Sci. Inf. Technol., vol. 1, no. 1, 2021, doi: 10.52088/ijesty.v1i1.36.
A. N. Ikhsan, Y. Azmiati, U. Delvianti, and I. Syauqiah, “KARAKTERISTIK BIOSORBEN PELEPAH NIPAH (Nypa Fruticans) UNTUK PENURUNAN KADAR LOGAM BERAT AIR MERKURI (Hg),†Jukung (Jurnal Tek. Lingkungan), vol. 7, no. 1, pp. 46–55, 2021, doi: 10.20527/jukung.v7i1.10814.
M. Meriatna, R. Afriani, L. Maulinda, S. Suryati, and Z. Zulmiardi, “OPTIMASI ADSORPSI ION Pb2+ MENGGUNAKANKARBON AKTIF SEKAM PADI PADA FIXED BED COLUMN DENGAN PENDEKATAN RSM (RESPONSE SURFACE METHODOLOGY),†J. Teknol. Kim. Unimal, vol. 8, no. 1, p. 100, 2021, doi: 10.29103/jtku.v10i1.4182.
R. Kusumawardani, T. A. Zaharah, and L. Destiarti, “Adsorpsi kadmium(II) menggunakan adsorben selulosa ampas tebu teraktivasi asam nitrat,†J. Kim. Khatulistiwa, vol. 7, no. 3, pp. 75–83, 2018.
A. Ghosh, D. Chakravorty, M. Rahaman, and S. Bose, Waste Water Recycling and Management. Springer Singapore, 2019.
G. Pari, “The Effect of Cellulose Incorporation on Charcoal-Carbon Structure . Part I : The Influence of Carbonisation Temperature,†J. Penelit. Has. Hutan, vol. 29, no. 002, pp. 33–45, 2011.
L. Velarde, M. S. Nabavi, E. Escalera, M. L. Antti, and F. Akhtar, “Adsorption of heavy metals on natural zeolites: A review,†Chemosphere, vol. 328, no. October 2022, p. 138508, 2023, doi: 10.1016/j.chemosphere.2023.138508.
N. N. W. Robby Irsan, “PEMANFAATAN SERBUK PELEPAH NIPAH (Nypa fruticans) UNTUK DESALINASI DI MUARA SUNGAI KAKAP,†J. Teknol. Lingkung. Lahan Basah, vol. 2, no. 1, pp. 1–10, 2014, doi: 10.26418/jtllb.v2i1.7297.
A. I. Ferraz, T. Tavares, and J. A. Teixeira, “Cr(III) removal and recovery from Saccharomyces cerevisiae,†Chem. Eng. J., vol. 105, no. 1–2, pp. 11–20, 2004, doi: 10.1016/j.cej.2004.07.009.
S. R. Rumiati, Refilda, E. Munaf, and Aziz Hermansyah, “Biosorption of lead(II) and copper(II) from aqueous solution by Nypa frutican husk,†Chem. Pharm. Res., vol. 7, no. 8, pp. 175–185, 2015.
S. Arivoli, V. Marimuthu, and A. R. M. Jahangir, “Kinetics of batch adsorption of iron (II) ions from aqueous solution using activated carbon from Strychnos nux-vomica L,†Int. J. Sci. Eng. Res., vol. 4, no. 12, pp. 407–417, 2013.
I. Syauqiah, M. Elma, D. P. Mailani, and N. Pratiwi, “Activated carbon from Nypa (Nypa fruticans) leaves applied for the Fe and Mn removal,†IOP Conf. Ser. Mater. Sci. Eng., vol. 980, no. 1, 2020, doi: 10.1088/1757-899X/980/1/012073.
N. Thaiyibah, Alimuddin, and A. S. Panggabean, “PEMBUATAN DAN KARAKTERISASI MEMBRAN SELULOSA ASETAT-PVC DARI ECENG GONDOK (Eichhornia crassipes) UNTUK ADSORPSI LOGAM TEMBAGA (II),†J. Kim. Mulawarman, vol. 14, no. 1, pp. 29–35, 2016.
P. Kongsune, S. Rattanapan, and R. Chanajaree, “The removal of Pb2+ from aqueous solution using mangosteen peel activated carbon: Isotherm, kinetic, thermodynamic and binding energy calculation,†Groundw. Sustain. Dev., vol. 12, no. June 2020, p. 100524, 2021, doi: 10.1016/j.gsd.2020.100524.
M. Nasruddin and D. Farid Mulana, “ADSORPSI ION LOGAM Cr (VI) DENGAN MENGGUNAKAN KARBON AKTIF DARI TEMPURUNG KEMIRI (ALEURITES MOLUCCANA),†Pascasarj. Univ. Syiah Kuala, vol. 9, no. 4, pp. 117–125, 2017.
A. Bayu, D. Nandiyanto, R. Oktiani, and R. Ragadhita, “Indonesian Journal of Science & Technology How to Read and Interpret FTIR Spectroscope of Organic Material,†Indones. J. Sci. Technol., vol. 4, no. 1, pp. 97–118, 2019.
M. Busyairi, F. Firlina, E. Sarwono, and S. Saryadi, “Pemanfaatan Serbuk Kayu Meranti Menjadi Karbon Aktif Untuk Penurunan Kadar Besi (Fe), Mangan (Mn) Dan Kondisi Ph Pada Air Asam Tambang,†J. Sains &Teknologi Lingkung., vol. 11, no. 2, pp. 87–101, 2019, doi: 10.20885/jstl.vol11.iss2.art1.
V. A. Mentari and S. Maulina, “Perbandingan Gugus Fungsi dan Morfologi Permukaan Karbon Aktif dari Pelepah Kelapa Sawit Menggunakan Aktivator Asam Fosfat (H3PO4) dan Asam Nitrat (HNO3),†Talent. Conf. Ser. Sci. Technol., vol. 1, no. 2, pp. 204–208, 2018, doi: 10.32734/st.v1i2.299.
M. A. Astari and B. Utami, “Uji Daya Adsorpsi Adsorben Kombinasi Sekam Padi dan Bagasse Fly Ash untuk Menjerap Logam Cu pada Sistem Batch,†Proceeding Biol. Educ. Conf., vol. 15, no. 1, pp. 766–774, 2018.
DOI: https://doi.org/10.52088/ijesty.v3i2.443
Article Metrics
Abstract view : 0 timesPDF - 0 times
Refbacks
- There are currently no refbacks.
Copyright (c) 2023 Meriatna, Lukman Hakim, Masrullita Masrullita, Zulmiardi Zulmiardi, Suri Atika