Methyl Orange Absorption Using Chitosan from Shrimp Skin as an Adsorbent
Abstract
In the coloring process, the textile industry generally uses synthetic (artificial) dyes, methyl orange (MO). In this study, the adsorption of methyl orange (MO) dye with chitosan was investigated in a series of batch laboratory studies. The adsorption equilibrium study used a MO solution with a concentration of 10 to 50 mg/L with an adsorbent weight of 3 g put into an Erlenmeyer and shaken until the adsorption reached an equilibrium condition. Meanwhile, the adsorption kinetics used a MO solution with an initial concentration of 10 and 20 mg/L with a volume of 100 mL with an adsorbent weight of 3 g and the solution was adjusted to pH 2. Effective operating parameters such as pH, initial concentration of dye (C0) and contact time at adsorption has been investigated. The results showed that the adsorption capacity of methyl orange (MO) dye from chitosan increased with an increasing acid content, and it was found that a solution of pH 2 was the optimal pH value for MO adsorption. The adsorption parameters for the Langmuir and Freundlich isotherms were determined by nonlinear regression and the equilibrium data were best explained by the Langmuir isotherm model, this was indicated by the high value of the correlation coefficient (R2), which was 0.9595. The maximum adsorption capacity was 0.1297 mg/g. Adsorption kinetics can be successfully applied to pseudo second-order kinetic models. The pseudo second-order model results show that the adsorption process is controlled by chemical sorption (chemisorption).
Keywords
Full Text:
PDFReferences
D. M. Maddox, A. Mayfield, and N. H. Poritz, “Distribution of yellow starthistle (Centaurea solstitialis) and Russian knapweed (Centaurea repens),†Weed Sci, vol. 33, no. 3, pp. 315–327, 1985.
C. D. Hernández-Origel et al., “Use of Eichhornia Crassipes as a Bioadsorbent for the Removal of Methyl Orange and Meth-ylene Blue Present in Residual Solutions,†Journal of Ecological Engineering, vol. 23, no. 9, 2022.
J. Fu, F. Yang, and Z. Guo, “The chitosan hydrogels: From structure to function,†New Journal of Chemistry, vol. 42, no. 21, pp. 17162–17180, 2018.
A. Hernández-Rangel et al., “Fabrication and in vitro behavior of dual-function chitosan/silver nanocomposites for potential wound dressing applications,†Materials Science and Engineering: C, vol. 94, pp. 750–765, 2019.
I. Aranaz et al., “Cosmetics and cosmeceutical applications of chitin, chitosan and their derivatives,†Polymers (Basel), vol. 10, no. 2, p. 213, 2018.
E. Fakhri et al., “Chitosan biomaterials application in dentistry,†Int J Biol Macromol, vol. 162, pp. 956–974, 2020.
J. Desbrières and E. Guibal, “Chitosan for wastewater treatment,†Polym Int, vol. 67, no. 1, pp. 7–14, 2018.
I. O. Saheed, W. Da Oh, and F. B. M. Suah, “Chitosan modifications for adsorption of pollutants–A review,†J Hazard Mater, vol. 408, p. 124889, 2021.
L. Dai et al., “Calcium-rich biochar from crab shell: an unexpected super adsorbent for dye removal,†Bioresour Technol, vol. 267, pp. 510–516, 2018.
X. Castillo et al., “A cheap mesoporous silica from fly ash as an outstanding adsorbent for sulfate in water,†Microporous and Mesoporous Materials, vol. 272, pp. 184–192, 2018.
E. S. Priya and P. S. Selvan, “Water hyacinth (Eichhornia crassipes)–An efficient and economic adsorbent for textile effluent treatment–A review,†Arabian Journal of Chemistry, vol. 10, pp. S3548–S3558, 2017.
Ç. Kıvılcımdan Moral and M. Yıldız, “Alginate production from alternative carbon sources and use of polymer based adsorbent in heavy metal removal,†Int J Polym Sci, vol. 2016, 2016.
L. Rumaropen, B. Mangallo, and M. F. Islam, “POTENSI KITOSAN DARI LIMBAH CANGKANG UDANG Penaeus mono-don ASAL BINTUNI SEBAGAI BIOSORBEN LIMBAH ORGANIK DAN LOGAM BERAT PADA LIMBAH CAIR PLTD MANOKWARI,†Jurnal Natural, vol. 17, no. 1, pp. 18–25, 2021.
A. Ahmad, K. Khabibi, R. Nuryanto, and A. Haris, “Adsorbsi Ion Tembaga (Ii) Dengan Kitosan Dari Kulit Udang Putih yang Termodifikasi Tripolifosfat,†Media Bina Ilmiah, vol. 14, no. 6, pp. 2781–2790, 2020.
H. Aldila, A. Asmar, V. A. Fabiani, D. Y. Dalimunthe, M. Megiyo, and R. Irwanto, “Pengaruh Temperatur Deproteinasi Pada Deasetilasi Kitin Cangkang Udang Krosok (Penaeus semisulcatus) Terhadap Adsorpsi Logam Besi (Fe),†Stannum: Jurnal Sains dan Terapan Kimia, vol. 2, no. 1, pp. 31–35, 2020.
Muhammad, T. G. Chuah, Y. Robiah, A. R. Suraya, and T. S. Y. Choong, “Single and binary adsorptions isotherms of Cd (II) and Zn (II) on palm kernel shell based activated carbon,†Desalination Water Treat, vol. 29, no. 1–3, pp. 140–148, 2011.
E. E. Jasper, V. O. Ajibola, and J. C. Onwuka, “Nonlinear regression analysis of the sorption of crystal violet and methylene blue from aqueous solutions onto an agro-waste derived activated carbon,†Appl Water Sci, vol. 10, no. 6, pp. 1–11, 2020.
I. Aranaz et al., “Functional characterization of chitin and chitosan,†Curr Chem Biol, vol. 3, no. 2, pp. 203–230, 2009.
S. Nethaji, A. Sivasamy, and A. B. Mandal, “Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass,†International journal of environmental sci-ence and technology, vol. 10, pp. 231–242, 2013.
J. F. M. Velez, Y. Shashoua, K. Syberg, and F. R. Khan, “Considerations on the use of equilibrium models for the characterisa-tion of HOC-microplastic interactions in vector studies,†Chemosphere, vol. 210, pp. 359–365, 2018.
J.-S. Cao, J.-X. Lin, F. Fang, M.-T. Zhang, and Z.-R. Hu, “A new absorbent by modifying walnut shell for the removal of ani-onic dye: kinetic and thermodynamic studies,†Bioresour Technol, vol. 163, pp. 199–205, 2014.
P. K. Malik, “Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36,†Dyes and pigments, vol. 56, no. 3, pp. 239–249, 2003.
DOI: https://doi.org/10.52088/ijesty.v3i2.431
Article Metrics
Abstract view : 0 timesPDF - 0 times
Refbacks
- There are currently no refbacks.
Copyright (c) 2023 Meriatna Meriatna, Sanda Mulia Utari, Rizka Mulyawan, Muhammad Muhammad